It is known that globalization has led first- and second-tier cities’ urban restructuring trajectories, excreted pressures, and caused tremendous socioeconomic volatility. This resulted in marginalized communities in dire of social empowerment, employment structure variance, and industry sectoral adjustment. Moreover, recent successive climate and health crisis unfolded and affirmed the state of our urban incompetence to sustain socioeconomic resilience or otherwise; lacking swift responses in providing critical management and services, cites are facing multifaceted challenges. Urban well-being and resilience are at stake. Although the environmental and health dimensional effects are apparent, this study ascertains that the transept multi-scalar analysis within the urban socioeconomic structure is crucial in sustaining core resilience to foster health and well-being of the community. As an integral part of the investigation, the revised DPSIR assessment framework is applied to evaluate the sectoral shift; spatial structure disarray and urban codependence degree are examined within the Taipei metropolitan area (TMA), a medium size but densely populated metropolitan area in Taiwan. The place-based DPSIR analysis ascertained the states and impacts in TMA: (1) A population decline speeded the restructuring of the urban core, while the impact of demographic aging and shrinkage rate mandates proper management and planning responses to the decline process; (2) the socioeconomic state effect is determined but does not critically affect the periphery zone, while an uneven demographic shift within the urban core necessitates dynamic adjustment responses to appropriately provide intergenerational services; (3) the uneven sector redistribution stimulated the core’s spatial and structural inter-dependency with peripheral zones, requiring governance with tighter cross-administration cooperation among respective public sectors; and (4) facing the sector/temporal and demographic pressure, urban cohesiveness in the TMA is greatly affected, which in turn disrupts the resilience pathway toward a cohesion. The study ascertained that the revised DPSIR framework could provide cities facing pressing socioeconomic drivers with effective analysis to allocate pressures, states, and impacts and formulate the necessary responses. To assure the socioeconomic resilience and urban cohesiveness, planning policy should carefully monitor and evaluate socio-demographic and sector redistribution factors to promote the urban resilience.
This study evaluated the hydrolysis and photolysis kinetics of pyraclostrobin in an aqueous solution using ultra-high-performance liquid chromatography–photodiode array detection and identified the resulting metabolites of pyraclostrobin by hydrolysis and photolysis in paddy water using high-resolution mass spectrometry coupled with liquid chromatography. The effect of solution pH, metal ions and surfactants on the hydrolysis of pyraclostrobin was explored. The hydrolysis half-lives of pyraclostrobin were 23.1–115.5?days and were stable in buffer solution at pH 5.0. The degradation rate of pyraclostrobin in an aqueous solution under sunlight was slower than that under UV photolysis reaction. The half-lives of pyraclostrobin in a buffer solution at pH 5.0, 7.0, 9.0 and in paddy water were less than 12?h under the two light irradiation types. The metabolites of the two processes were identified and compared to further understand the mechanisms underlying hydrolysis and photolysis of pyraclostrobin in natural water. The extracted ions obtained from paddy water were automatically annotated by Compound Discoverer software with manual confirmation of their fragments. Two metabolites were detected and identified in the pyraclostrobin hydrolysis, whereas three metabolites were detected and identified in the photolysis in paddy water. 相似文献
为探究冻融循环后尾矿物理力学特性的变化特征,使用高低温试验箱和应变控制式三轴剪力仪对处于不同初始条件下的尾矿砂进行不排水不固结试验,揭示了尾矿砂的抗剪强度参数、不同围压条件下的变形模量与冻融循环次数、含水率之间的关系。结果表明:相同含水率条件下,随冻融循环次数增加,尾矿砂黏聚力先减小后趋于稳定,内摩擦角先增大后减小,围压100 k Pa和200 k Pa时变形模量逐渐减小,围压300 k Pa时变形模量呈现先减小后缓慢增大的趋势;相同冻融循环次数条件下,随尾矿砂含水率增加,其黏聚力先增加后减小、内摩擦角不断减小;不同围压条件下变形模量在总体上均呈现出不断减小的变化趋势,围压200 k Pa时变形模量总的衰减量最大,100k Pa次之,300 k Pa最小。 相似文献